Sulfur Biogeochemical Cycling and Redox Dynamics in a Shale‐Dominated Mountainous Watershed
نویسندگان
چکیده
Abstract Sulfur (S) is an essential macronutrient and important component of the earth’s crust, its cycling has critical impacts on trace metal mobility, water quality, human health. Pyrite weathering primary pathway by which sulfur enters surface waters. However, biogeochemical in soils river corridor mediates sulfate exports. In this study, we identified major forms across multiple compartments scales a pristine mountainous watershed, including shale bedrock profiles, hillslope soils, alluvial floodplain sediments, order to provide insight into hydrologically variable alpine system. X‐ray absorption near‐edge spectroscopy (XANES) analysis profiles showed clear evidence pyrite oxidation sulfate, with large accumulations intermediate S(0) (20%–53%). Micro‐scale XANES reprecipitation at fracture surfaces within permanently saturated zone. Organic dominated S speciation shallow soil sediment, little reduced inorganic S. mackinawite formation, representing active reduction, was observed oxbow sediments weathered underlying sediments. Further reduction from aqueous isotopic groundwater transects Fe‐reducing meander, whereas increases pore concentrations implied other locations. The data present integrated picture shale‐dominated where riverine exports are mediated biological cycling, particularly redox‐stratified temporally dynamic hyporheic zone
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ژورنال
عنوان ژورنال: Journal Of Geophysical Research: Biogeosciences
سال: 2022
ISSN: ['2169-8961', '2169-8953']
DOI: https://doi.org/10.1029/2021jg006769